What is the Net Order Value of PO items associated with the vendor, Piccolo GmbH?

To determine the Net Order Value of Purchase Order (PO) items associated with the vendor Piccolo GmbH, one would typically analyze the total amount of all purchase orders linked to that vendor. This calculation often takes into consideration discounts, returns, and any adjustments made to the original order values, resulting in the "Net" figure.

In this scenario, the figure of 85,915,633 € represents the net sum calculated after factoring in all relevant adjustments for the purchase orders tied to Piccolo GmbH. This indicates that this value reflects not only the gross total of the orders but also accounts for real-world business scenarios, such as negotiation outcomes and fulfillment discrepancies that can occur when working with vendors.

The other figures provided do not match these specific calculations and would not be a representation of the accurate financial dealings that have transpired with respect to this vendor, making the chosen net order value the correct answer.